Not really a big difference as the 7225PE is also in the same class as the 7020e, 7020i and 7220 PE series. Here is how these amplifiers evolved:
NAD 3020 integrated amp came first (later available as 3020A, 3020B, 3020e and 3020i)
NAD 4020 tuner was added as its matching analog tuner (later available as 4020A and 4020B, all analog tuners)
NAD 4220 tuner, digital version of the 4020 analog tuner
NAD 4225 tuner, upgraded version of the 4220 digital tuner
NAD 3220 PE integrated amp, which is essentially the 3020e with the power envelop circuitry added
NAD 3225 PE integrated amp, essentially the same 3020i preamplifier section coupled with a different and more powerful poweramp section, also with power envelop circuitry added
NAD 7020 receiver (a combination of the 3020 and 4020)
NAD 7020e and 7020i receivers (a combination of the 3020e and 3020i and 4220 tuner)
NAD 7220 PE receiver (a combination of the 3020e and 4220 tuner, with power envelop circuitry added)
NAD 7225 PE receiver (a combination the the preamp section of the 3020i, a more powerful poweramp section with power envelop circuitry and the 4225 tuner)
Infact the NAD 7020i and 7225 PE share the same service manual
This is all essentially one big family. There are matching Cassette Decks for these series as well.
So essentially my comments about the 7220 PE, holds good for the 7225 PE as well.