There is no CEC implementation on the PC graphics card so it should never interfere with the AVR power state (on/off). Is it possible that the remote codes are similar for the two devices? Can you try powering on the TV and AVR without the remotes and see if you can reproduce the problem?
Another possibility is HDMI CEC signals between TV and AVR. Try turning this feature off on both your TV & AVR. See if that solves the problem.
Another possibility is HDMI CEC signals between TV and AVR. Try turning this feature off on both your TV & AVR. See if that solves the problem.