Is a combination of a AV receiver with a multi-ch amp good ?? Presumably the AVR would do the processing or act as Preamp.
It all depends upon what your objective is.
As step 1, for a long time, people have been using an AVR with a dedicated two channel amp to power the front speakers. If you look at an movie, nearly 80% of the audio data is sent to the front speakers. If the amplification of this data is handled by a dedicated amp, you get better clarity and dialogues are clearer.
Setp two is to use either a 3 channel amp, or three mono blocks to amplify the fronts and the centre channel. This increases the dialogue clarity even more.
The final step is something that has become popular over the last two odd years. Companies such as Outlaw Audio and Emotiva have worked on bringing out a surround sound processor that is just a decoder and a multi channel pre-amplifier. You take the analogue out from this processor and feed it to a 5 channel to 7 channel amplifier.
If you are looking at increasing the power for just power's sake, I would suggest you look at other things such as room acoustics and equalisation to improve sound. If,
after this, you want to hear all sounds and dialogues clearly at a reasonable amplitude, power amplification is the way to go.
Cheers